Porous ionic liquids combining alkylphosphonium halides with ZIF-8 absorb large amounts of carbon dioxide that can be catalytically coupled with epoxides to form cyclic carbonates. High activity and selectivity under mild reaction conditions points towards a new promising, high-performing, sustainable family of sorbents for simultaneous carbon capture and transformation.
Y. Zhou, J. Avila, N. Berthet, S. Legrand, C. C. Santini, M. Costa Gomes and V. Dufaud, Chem. Commun., 2021, 57, 7922 DOI: 10.1039/D1CC02642A
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