Issue 80, 2021
From the journal:

Chemical Communications

Constructing a triangular metallacycle with salen–Al and its application to a catalytic cyanosilylation reaction†

Jun Xu,‡a   Yueyue Zhang,‡a   Jinjin Zhang,a   Yang Li,a   Bo Li,a   Huayu Qiu, ORCID logo a   Pengfei Zhang ORCID logo *a  and  Shouchun Yin ORCID logo *a  

* Corresponding authors

a College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, P. R. China
E-mail: pfzhang@hznu.edu.cn, yinsc@hznu.edu.cn
Fax: +8657128865077
Tel: +8657128865077

Abstract

A triangular metallosalen-based metallacycle was constructed in quantitative yield by the self-assembly of a 180° bis(pyridyl)salen–Al complex and a 60° diplatinum(II) acceptor in a 1 : 1 stoichiometric ratio. This metallacycle was then successfully used to cyanosilylate a wide range of benzaldehydes with trimethylsilyl cyanide.

Graphical abstract: Constructing a triangular metallacycle with salen–Al and its application to a catalytic cyanosilylation reaction

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Article information

DOI
https://doi.org/10.1039/D1CC04577F
Article type
Communication
Submitted
18 Aug 2021
Accepted
10 Sep 2021
First published
11 Sep 2021

Chem. Commun., 2021,57, 10399-10402

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Constructing a triangular metallacycle with salen–Al and its application to a catalytic cyanosilylation reaction

J. Xu, Y. Zhang, J. Zhang, Y. Li, B. Li, H. Qiu, P. Zhang and S. Yin, Chem. Commun., 2021, 57, 10399 DOI: 10.1039/D1CC04577F

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