Emergence of practical fluorescence in a confined space of nanoporous silica: significantly enhanced quantum yields of a conjugated molecule

Abstract

The fluorescence of benzanthrone, which is a conjugated molecule bearing a carbonyl group, is activated by confinement in a pore with a diameter close to the molecular size. An intense emission originating from the aromatic character π–π* transition is achieved through suppression of the nonradiative n–π* transition by strong hydrogen bonding between carbonyl groups and silanol groups with a micropore-filling effect in the nanospace.