Issue 8, 2021

Synthesis, structure, and fluorescence properties of coordination polymers of 3,5-bis(1′,2′,4′-triazol-1′-yl) pyridine

Abstract

Four Co, Zn/Cd-containing coordination polymers incorporating the 3,5-bis(1′,2′,4′-triazol-1′-yl) pyridine ligand, namely [Co(fa)2(btap)2] (1), [Zn3(btc)2(btap)4(H2O)2] (2), [Cd3(btc)2(btap)(H2O)6] (3) and [Cd(oa)(btap)] (4), were synthesized by the solvothermal method. Compound 1 featured a two-dimensional (2D) 4-connected framework with the point symbol of (44)(62) topology. The structure of 2 was a 2D (2,3,4)-connected framework with (83)2(85·12)2(8)3 topology. Compound 3 had approximately a planar 2D network with (63) topology. Compound 4 possessed a 4-connected three-dimensional (3D) structure with (126)(12)2 topology. The photoluminescence properties of compounds 3 and 4 have been studied in the solid-state and solvent suspension at ambient temperature as well.

Graphical abstract: Synthesis, structure, and fluorescence properties of coordination polymers of 3,5-bis(1′,2′,4′-triazol-1′-yl) pyridine

Supplementary files

Article information

Article type
Paper
Submitted
14 Nov 2020
Accepted
13 Jan 2021
First published
14 Jan 2021

CrystEngComm, 2021,23, 1744-1755

Synthesis, structure, and fluorescence properties of coordination polymers of 3,5-bis(1′,2′,4′-triazol-1′-yl) pyridine

H. Yu and J. Sun, CrystEngComm, 2021, 23, 1744 DOI: 10.1039/D0CE01649G

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