One-step solvothermal synthesis and growth mechanism of well-crystallized β-Ga2O3 nanoparticles in isopropanol

Abstract

Simple liquid-phase approaches for the synthesis of nanomaterials are attractive because their low costs, reduced nanoparticle aggregation, and compatibility with subsequent liquid processes widen the application scope of the resulting materials. This would be particularly interesting for β-Ga₂O₃ nanoparticles, which often suffer from aggregation issues during their synthesis processes. In this paper, we report a one-step synthesis of β-Ga₂O₃ nanoparticles in supercritical isopropanol. By simply heating Ga(NO₃)₃ in isopropanol at 400 °C for 24 hours, β-Ga₂O₃ nanoparticles with a size of ∼100 nm are obtained without requiring additional calcination in air. A structural characterization comprising X-ray diffraction, scanning electron microscopy, selected-area electron diffraction with transmission electron microscopy, and X-ray absorption fine structure measurements suggest that the synthesis process involves an initial conversion of Ga(NO₃)₃ to Ga(Oi-Pr)₃ or a related species at 80 °C, which then transforms into γ-Ga₂O₃ nanoparticles upon increasing the temperature, to eventually produce β-Ga₂O₃ nanoparticles most likely via a dissolution and recrystallization process.