Formation of HCN+ in collisions of N+ and N2+ with a self-assembled propanethiol surface on gold

Abstract

Collisions of N⁺ and N₂⁺ with C3 hydrocarbons, represented by a self assembled monolayer of propanethiol on a polcrystalline gold surface, were investigated by experiments over the incident energy range between 5 eV and 100 eV. For N⁺, formation of HCN⁺ is observed at incident energies of projectile ions as low as 20 eV. In the case of N₂⁺ projectile ions, the yield of HCN⁺ increased above zero only at incident energies of about 50 eV. This collision energy in the laboratory frame corresponds to an activation energy of about 3 eV to 3.5 eV. In the case of N⁺ projectile ions, the yield of HCN⁺ was large for most of the incident energy range, but decreased to zero at incident energies below 20 eV. This may indicate a very small energy threshold for the surface reaction between N⁺ and C3 hydrocarbons of a few tenths of an eV. Such a threshold for the formation of HCN⁺ may exist also for collisions of N⁺ with an adsorbed mixture of hydrocarbon molecules.