Linear group 13 EE triple bonds

Abstract

The unexpected linear group 13 EE triple bonds were herein uncovered with the D_3h-symmetry E₂M₅⁺ (M = Li, Na, and K) clusters, where the linear M–EE–M form is perfectly surrounded by M₃ motifs. The increasing nonbonded electron density of the heavier main-group elements is the key issue for the trans-bent geometry, and yet it is strongly suppressed in E₂M₅⁺, creating two degenerate π bonds and one multi-center σ bond.