A chromatography-free total synthesis of a ferrocene-containing dendrimer exhibiting the property of recognizing 9,10-diphenylanthracene

Abstract

Molecules comprising several ferrocene residues constitute an intriguing group of compounds for various applications. Here, the total synthesis of a new example of a ferrocene-containing dendrimer is presented. The target compound was obtained in excellent combined yield (65%) employing facile, chromatography-free methods at each step. Interesting findings, meeting the dynamic covalent chemistry concept, are reported. Cyclic voltammetry analyses revealed one pair of current signals for the ferrocene moieties. Ultimately, the synthesized ferrocene-containing dendrimer has been used as an innovative recognition material for 9,10-diphenylanthracene, a polycyclic aromatic hydrocarbon, with the limit of detection value equal to 0.06 μM.