Advancement in functionalized luminescent frameworks and their prospective applications as inkjet-printed sensors and anti-counterfeit materials

Abstract

Supramolecular luminescent frameworks with conjugated architectures exhibits interesting photophysical properties with phenomenal chemical and thermal stability. This has instigated global researchers towards its extensive application in toxic analyte detection and the formulation of anti-counterfeit materials. In correlation with this present scenario, luminescent metal–organic frameworks (LMOFs), possessing tailorable structural and functional properties and exceptional physicochemical features, have been categorized as emerging ‘smart materials’. Interestingly, LMOFs have assisted in the rapid development of an effectual sensing platform and swift fabrication of anti-counterfeit materials on desirable substrates with the aid of ‘Inkjet Printing’, which is a viable, low-cost, and high-resolution technology. Inkjet printing is an excellent material deposition technique in the modern era owing to its easy settling over flexible substrates, simplistic emergence of large area image patterns with improved throughput, minimal cost, explicit resolution, and least waste generation. The present review provides state-of-the-art progress on LMOFs based (i) luminescent security ink fabrication with static and dynamic multinodal luminescent materials and (ii) sensory device formulation for the easy and instantaneous recognition of hazardous analytes through the ‘Inkjet Printing’ technology. This techno-chemical integration will be certainly beneficial to prevent the growth of counterfeit materials and monitor the bioaccumulation of hazardous analytes in our ecological system.