The design of dual-switch fluorescence intensity ratio thermometry with high sensitivity and thermochromism based on a combination strategy of intervalence charge transfer and up-conversion fluorescence thermal enhancement

Abstract

Currently, the temperature sensing performances of inorganic photoluminescence materials based on fluorescence intensity ratio technology have become a research hotspot in the optical thermometry field due to their non-contact sensing, fast response and high stability. However, several problems have obstructed the development of optical temperature sensing materials, including low sensitivity and narrow temperature measurement ranges. In view of the above dilemma, a new optical thermometer La₂Mo₃O₁₂:Yb³⁺,Pr³⁺ designed based on the combination strategy of intervalence charge transfer and up-conversion fluorescence thermal enhancement was developed. Under excitation at 450 nm, the thermometer can work in a range from 298 to 648 K and the relative sensitivity reaches as high as 2.000% K⁻¹ at 648 K. Under excitation at 980 nm, the thermometer can sense temperature with a wide range from 298 to 748 K and the relative sensitivity reaches as high as 4.325% K⁻¹ at 598 K. A dual-switch optical temperature sensing material with high-sensitivity and a wide temperature measurement range has been successfully developed. Our research design strategies will give inspiration to the research on multi-switch temperature sensing materials with high sensitivity and a wide temperature measurement range.