Issue 20, 2021

Tuning luminescence of didysprosium single-molecule magnets with a π-conjugated/non-conjugated bridging ligand

Abstract

Herein, we reported two didysprosium single-molecule magnets constructed with {Dy(bbpen)(MeOH)} subunits and a π-conjugated tpb or non-conjugated tpcb bridging ligand. The former exhibits extremely weak luminescence that makes it difficult to simulate its emission spectra. However, the later shows obviously enhanced and well-resolved luminescence, which helps us to gain knowledge about the magneto-optical correlation and the relevant magnetic energy levels.

Graphical abstract: Tuning luminescence of didysprosium single-molecule magnets with a π-conjugated/non-conjugated bridging ligand

Supplementary files

Article information

Article type
Communication
Submitted
19 Mar 2021
Accepted
14 Apr 2021
First published
14 Apr 2021

Dalton Trans., 2021,50, 6778-6783

Tuning luminescence of didysprosium single-molecule magnets with a π-conjugated/non-conjugated bridging ligand

Y. Liu, B. Lyu, S. Du, G. Huang, Z. Ruan, S. Wu, J. Liu and M. Tong, Dalton Trans., 2021, 50, 6778 DOI: 10.1039/D1DT00908G

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