Issue 26, 2021

Selective encapsulation of a chloride anion in a 1H-pyrazole Cu2+ metallocage

Abstract

A self-assembled metallobox from copper(II) and two macrocycles containing 1H-pyrazole ligands has been prepared. The internal cavity of the box is able to selectively encapsulate a single chloride anion over any other halide anion.

Graphical abstract: Selective encapsulation of a chloride anion in a 1H-pyrazole Cu2+ metallocage

Supplementary files

Article information

Article type
Communication
Submitted
20 Apr 2021
Accepted
02 Jun 2021
First published
07 Jun 2021

Dalton Trans., 2021,50, 9010-9015

Selective encapsulation of a chloride anion in a 1H-pyrazole Cu2+ metallocage

J. Pitarch-Jarque, H. R. Jiménez, E. Kalenius, S. Blasco, A. Lopera, M. P. Clares, K. Rissanen and E. García-España, Dalton Trans., 2021, 50, 9010 DOI: 10.1039/D1DT01302E

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