Issue 31, 2021

Dihydrogen cleavage by a dimetalloxycarbene–borane frustrated Lewis pair

Abstract

A frustrated Lewis pair of dititanoxycarbene [(Ti(N[tBu]Ar)3)2(μ-CO2)] (Ar = 3,5-Me2C6H3) and B(C6F5)3 cleaved dihydrogen under ambient conditions to give the zwitterionic formate [(Ti(N[tBu]Ar)3)2(μ-OCHO-ηOO′)(B(C6F5)3)] and the hydrido borate [Ti(N[tBu]Ar)3][HB(C6F5)3].

Graphical abstract: Dihydrogen cleavage by a dimetalloxycarbene–borane frustrated Lewis pair

Supplementary files

Article information

Article type
Communication
Submitted
09 Jul 2021
Accepted
19 Jul 2021
First published
20 Jul 2021

Dalton Trans., 2021,50, 10692-10695

Author version available

Dihydrogen cleavage by a dimetalloxycarbene–borane frustrated Lewis pair

A. Paparo, A. L. P. Nguyen, J. S. Silvia, T. P. Spaniol, L. Maron, C. C. Cummins and J. Okuda, Dalton Trans., 2021, 50, 10692 DOI: 10.1039/D1DT02273C

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