Visible light induced hydrophosphinylation of unactivated alkenes catalyzed by salicylaldehyde

Zeqin Yuan; Simin Wang; Miaomiao Li; Tian Chen; Jiaye Fan; Fuying Xiong; Qianggen Li; Ping Hu; Bi-Qin Wang; Peng Cao; Yang Li

doi:10.1039/D1GC00374G

Visible light induced hydrophosphinylation of unactivated alkenes catalyzed by salicylaldehyde†

Zeqin Yuan,^a Simin Wang,^a Miaomiao Li,^a Tian Chen,^a Jiaye Fan,^a Fuying Xiong,^a Qianggen Li,^a Ping Hu,^a Bi-Qin Wang,^a Peng Cao^a and Yang Li

*^a

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^a College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China
E-mail: yangli@sicnu.edu.cn

Abstract

An air and water insensitive visible light induced hydrophosphinylation of unactivated alkenes is reported. A small amount of a simple and cheap compound, salicylaldehyde, is used as a photosensitizer. The reaction is carried out in a basic aqueous solution which enables the deprotonated salicylaldehyde to show visible light absorption.

Green Chemistry

Visible light induced hydrophosphinylation of unactivated alkenes catalyzed by salicylaldehyde†

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Visible light induced hydrophosphinylation of unactivated alkenes catalyzed by salicylaldehyde

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