Accurately manipulating hierarchical flower-like Fe2P@CoP@nitrogen-doped carbon spheres as an efficient carrier material of Pt-based catalyst

Abstract

Fabrication of hierarchical porous catalysts with a large specific surface area and tunable architecture provides an effective strategy to promote the catalytic performance of Pt-based catalysts. Herein, we design and construct hierarchical flower-like Fe₂P@CoP@nitrogen-doped carbon (Fe₂P@CoP@NDC) through a facile method, and synthesize Pt/Fe₂P@CoP@NDC porous spheres via acid pickling and depositing of Pt NPs. The morphology of Fe₂P@CoP@NDC is precisely manipulated by controlling the synthesis conditions, including the reaction time and the addition of a protective agent, and the protective growth mechanism of the hierarchical flower-like Fe₂P@CoP@NDC spheres is mentioned. Significantly, the Pt/Fe₂P@CoP@NDC catalyst exhibits 3.29 and 2.36 times higher mass activity and specific activity than those of commercial Pt/C for methanol oxidation, respectively. Furthermore, its residual mass activity after 1000 cycles is 5.77 times as much as that of the commercial Pt/C catalyst in acidic electrolytes. Based on exploration of the reaction kinetics of the Pt/Fe₂P@CoP@NDC catalyst, the excellent catalytic activity and durability are attributed to the unique porous structure with relatively open area and enlarged specific surface area, which can promote fast electron transport and charge transfer, resulting in quick reaction kinetics. Moreover, metal phosphides can effectively accelerate the oxidative removal of intermediates, accordingly improving the catalytic activity. Therefore, the Pt/Fe₂P@CoP@NDC material with these compositional and structural features is expected to be a promising electrochemical catalyst.