Issue 4, 2021

Deaminative carbonylative thioesterification of activated alkylamines with thiophenols under transition-metal-free conditions

Abstract

In this communication, a transition-metal-free deaminative carbonylation of activated alkylamines with thiophenols has been developed. Thioesters with various substituents were produced in moderate to good yields through Katritzky salt intermediates.

Graphical abstract: Deaminative carbonylative thioesterification of activated alkylamines with thiophenols under transition-metal-free conditions

Supplementary files

Article information

Article type
Research Article
Submitted
25 Nov 2020
Accepted
16 Dec 2020
First published
17 Dec 2020

Org. Chem. Front., 2021,8, 670-675

Deaminative carbonylative thioesterification of activated alkylamines with thiophenols under transition-metal-free conditions

F. Zhao and X. Wu, Org. Chem. Front., 2021, 8, 670 DOI: 10.1039/D0QO01479F

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