Clover leaf-shaped supramolecules assembled using a predesigned metallo-organic ligand

Qixia Bai; Tun Wu; Zhe Zhang; Lianghuan Xu; Zhengbin Tang; Yuming Guan; Ting-Zheng Xie; Mingzhao Chen; Peiyang Su; Heng Wang; Pingshan Wang; Xiaopeng Li

doi:10.1039/D1QO00336D

Clover leaf-shaped supramolecules assembled using a predesigned metallo-organic ligand†

Qixia Bai,‡^a Tun Wu,‡^a Zhe Zhang,*^ac Lianghuan Xu,^a Zhengbin Tang,^a Yuming Guan,^a Ting-Zheng Xie,

^a Mingzhao Chen,^a Peiyang Su,^a Heng Wang,^b Pingshan Wang

*^a and Xiaopeng Li

*^b

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* Corresponding authors

^a Institute of Environmental Research at Greater Bay Area; Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education; Guangzhou Key Laboratory for Clean Energy and Materials; Guangzhou University, Guangzhou 510006, China
E-mail: chemwps@csu.edu.cn, zhezhang2018@gzhu.edu.cn

^b College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, Guangdong 518055, China
E-mail: xiaopengli@szu.edu.cn

^c Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, China

Abstract

Inspired by the clover plant in nature, clover leaf-shaped supramolecular structures with three hexagons fused to create a triangular core were designed and self-assembled using a combination of Ru–Zn, Ru–Co, Ru–Mn or Ru–Ni metal ions. These results lay the foundation for further applications of heterometallic multinuclear metallo-supramolecules.

This article is part of the themed collections: FOCUS: Macrocyclic and supramolecular chemistry and Macrocycle-based Supramolecular Elements

Organic Chemistry Frontiers

Clover leaf-shaped supramolecules assembled using a predesigned metallo-organic ligand†

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Clover leaf-shaped supramolecules assembled using a predesigned metallo-organic ligand

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