Engineering defect clusters in distorted NaMgF3 perovskite and their important roles in tuning the emission characteristics of Eu3+ dopant ion

Abstract

An attempt has been made to explore various new defect clusters in distorted NaMgF₃ perovskite and their important role in tuning optical properties. We have tried to tailor the defect clusters and to understand the impact on the luminescence of the lanthanide, for example the Eu³⁺ ion. Defect engineering has been carried out by doping aliovalent dopant ions to create a charge imbalance in the matrix, which in turn led to the creation of various mono-, di- and new cluster vacancies. Such vacancies have been characterized by Electron Para-magnetic Resonance (EPR), Positron Annihilation Lifetime Spectroscopy (PALS) and Photoluminescence (PL) studies. The PALS data of both undoped and Eu³⁺ doped compounds confirmed that in addition to Mg mono vacancies, cluster vacancies with different configurations comprising Mg, Na and F atom vacancies also exist in the matrix. The PL study revealed that depending on the surrounding defect structure, three different types of Eu³⁺ components can be created. The position of the Eu³⁺ ion with respect to these cluster vacancies determines the respective emission profiles and the decay kinetics. It has been found that when Li⁺ ions are co-doped with Eu³⁺, there is a sudden change in the decay kinetics and the emission profiles. The PALS study revealed that Li⁺ co-doping modified the configuration of the vacancy clusters, which in turn changes the emission characteristics. The EPR study confirmed the presence of different types of F-centers (F, F₂, etc.) which are responsible for the host emission. Overall, this new study will be very helpful for a detailed understanding of the defect structures, in particular the cluster vacancies in distorted NaMgF₃ perovskite, which have a direct or indirect impact on many physical properties.