Y2O3:Yb3+, Tm3+/ZnO composite with a heterojunction structure and upconversion function for the photocatalytic degradation of organic dyes

Abstract

Endowing photocatalytic materials with a broader range of light responses is important for improving their performance and solar energy utilization. In this study, a simple sol–gel method was used to prepare Yb³⁺/Tm³⁺-co-doped Y₂O₃ upconversion materials and Y₂O₃:Yb³⁺, Tm³⁺/ZnO (Y/Z) composite photocatalysts for the photocatalytic degradation of dyes. The Y/Z composite photocatalyst achieved degradation rates of 38%, 95%, and 89% for methyl orange, methylene blue (MB), and acid chrome blue K dye solutions, respectively, within 30 minutes. The degradation efficiency for MB after three cycles of degradation was 86%. The spherical Y₂O₃:Yb³⁺, Tm³⁺ particles had diameters of 20–50 nm and attached to the ZnO nanosheets, forming a heterojunction structure with ZnO. Fluorescence spectroscopy showed that Y₂O₃:Yb³⁺, Tm³⁺ could convert near-infrared (NIR) light into three sets of ultraviolet light (290, 320, and 360 nm) under NIR excitation. Photoluminescence spectroscopy demonstrated that the photogenerated electron–hole pair recombination probability of the composite photocatalyst was significantly lower than that of ZnO nanosheets, thereby reducing the energy loss during the migration process. Furthermore, the addition of Y₂O₃:Yb³⁺, Tm³⁺ to ZnO substantially improved the absorption capacity for ultraviolet light, which enhanced the photocatalytic activity. A possible mechanism for the enhanced photocatalytic performance of the Y/Z composites was proposed based on the synergistic effect of heterojunction formation and the photoconversion process. The composite photocatalyst with upconversion characteristics and heterogeneous structure provides a new strategy for removing organic pollutants from water.