Efficient solar light-driven hydrogen generation using an Sn3O4 nanoflake/graphene nanoheterostructure

Abstract

Herein, we report Sn₃O₄ and Sn₃O₄ nanoflake/graphene for photocatalytic hydrogen generation from H₂O and H₂S under natural “sunlight” irradiation. The Sn₃O₄/graphene composites were prepared by a simple hydrothermal method at relatively low temperatures (150 °C). The incorporation of graphene in Sn₃O₄ exhibits remarkable improvement in solar light absorption, with improved photoinduced charge separation due to formation of the heterostructure. The highest photocatalytic hydrogen production rate for the Sn₃O₄/graphene nanoheterostructure was observed as 4687 μmol h⁻¹ g⁻¹ from H₂O and 7887 μmol h⁻¹ g⁻¹ from H₂S under natural sunlight. The observed hydrogen evolution is much higher than that for pure Sn₃O₄ (5.7 times that from H₂O, and 2.2 times from H₂S). The improved photocatalytic activity is due to the presence of graphene, which acts as an electron collector and transporter in the heterostructure. More significantly, the Sn₃O₄ nanoflakes are uniformly and parallel grown on the graphene surface, which accelerates the fast transport of electrons due to the short diffusion distance. Such a unique morphology for the Sn₃O₄ along with the graphene provides more adsorption sites, which are effective for photocatalytic reactions under solar light. This work suggests an effective strategy towards designing the surfaces of various oxides with graphene nanoheterostructures for high performance of energy-conversion devices.