The interesting luminescence behavior and rare nonlinear optical properties of the {Ag55Mo6} nanocluster

Kun Zhou; Li-Kai Yan; Yun Geng; Jiu-Yu Ji; Xin-Long Wang; Zhong-Min Su; Zheng-Guo Xiao

doi:10.1039/D1RA06569F

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The interesting luminescence behavior and rare nonlinear optical properties of the {Ag₅₅Mo₆} nanocluster†

Kun Zhou,

^ab Li-Kai Yan,

^a Yun Geng,

*^a Jiu-Yu Ji,^b Xin-Long Wang,

*^a Zhong-Min Su

^a and Zheng-Guo Xiao*^c

Author affiliations

* Corresponding authors

^a Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, Jilin, China
E-mail: gengy575@nenu.edu.cn, wangxl824@nenu.edu.cn

^b School of Petrochemical Engineering, Liaoning Petrochemical University, Fushun 113001, Liaoning, China

^c Department of Physics and Electronic Engineering, Tongren University, Tongren 554300, Guizhou, China
E-mail: xiangyunonlinear@gmail.com

Abstract

The remarkably reversible thermochromic luminescence behavior and the rare nonlinear optical (NLO) properties of the [Ag₅₅(MoO₄)₆(C [triple bond, length as m-dash] C^tBu)₂₄(CH₃COO)₁₈(CH₃COO)]·2H₂O ({Ag₅₅Mo₆} for short) nanocluster reported were investigated experimentally. The important contributions of Ag⁺, CC⁻ ions and MoO₄²⁻ groups to the NLO properties were proved by further density functional theory (DFT) calculations.

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Article information

DOI: https://doi.org/10.1039/D1RA06569F
Article type: Paper
Submitted: 01 Sep 2021
Accepted: 30 Nov 2021
First published: 03 Dec 2021
This article is Open Access

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RSC Adv., 2021,11, 38814-38819

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The interesting luminescence behavior and rare nonlinear optical properties of the {Ag₅₅Mo₆} nanocluster

K. Zhou, L. Yan, Y. Geng, J. Ji, X. Wang, Z. Su and Z. Xiao, RSC Adv., 2021, 11, 38814 DOI: 10.1039/D1RA06569F

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