A highly luminescent and stable copper halide ionic hybrid structure with an anionic CuBr2(tpp)2 module

Abstract

Here, we report a novel copper bromide ionic compound (bz-ted)CuBr₂(tpp)₂·H₂O (1, tpp = triphenylphosphine, and bz-ted = 1-benzyl-1,4-diazabicyclo[2.2.2]octan-1-ium) by a facile wet chemistry method. The inorganic module of the compound is CuBr₂⁻ coordinated to two tpp molecules, generating strong blue photoluminescence originating from the metal-to-ligand-charge-transfer (MLCT) process. The combination of both ionic bonds and covalent bonds in the hybrid cluster makes compound 1 strongly emissive, robust and solution-processable. Such a coordinated anionic inorganic module presents a new approach for the development of highly luminescent and stable copper halide ionic hybrid structures.