Functionalisation of MoS2 2D layers with diarylethene molecules

Abstract

Functionalisation of two-dimensional (2D) materials with stimuli-responsive molecules has been scarcely investigated. Here, MoS₂ layers obtained by chemical exfoliation are covalently and non-covalently functionalised using two photoswitchable diarylethene derivatives under their open- and closed-ring isomers. The choice of these light-responsive molecules is based on their excellent thermal irreversibility and fatigue resistance. The characterisation of the resultant molecular/2D heterostructures proves the successful anchoring of the molecules by both approaches as well as the influence that the driving interaction has on the photoswitching behaviour of the diarylethene isomers after their deposition on the 2D layer.