Issue 7, 2022

Enzyme-like catalysis by single chain nanoparticles that use transition metal cofactors

Abstract

We report a modular approach in which a noncovalently cross-linked single chain nanoparticle (SCNP) selectively binds catalyst “cofactors” and substrates to increase both the catalytic activity of a Cu-catalyzed alkyne-azide cycloaddition reaction and the Ru-catalyzed cleavage of allylcarbamate groups compared to the free catalysts.

Graphical abstract: Enzyme-like catalysis by single chain nanoparticles that use transition metal cofactors

Supplementary files

Article information

Article type
Communication
Submitted
04 Oct 2021
Accepted
15 Dec 2021
First published
15 Dec 2021

Chem. Commun., 2022,58, 985-988

Author version available

Enzyme-like catalysis by single chain nanoparticles that use transition metal cofactors

T. M. Xiong, E. S. Garcia, J. Chen, L. Zhu, A. J. Alzona and S. C. Zimmerman, Chem. Commun., 2022, 58, 985 DOI: 10.1039/D1CC05578J

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