Photochemical and electrochemical C–N borylation of arylhydrazines

Abstract

The C–N borylation of arylhydrazine hydrochlorides with bis(pinacolato)diboron was achieved under photochemical and electrochemical conditions, respectively. This novel and scalable transformation provides two efficient and mild transition-metal-free synthetic routes towards aryl boronate esters from easily available arylhydrazines.