Triple-decker complexes incorporating three distinct deck architectures

Abstract

The reactivity of the dilithioplumbole ([Li₂(thf)₂(μ,η⁵-L^Pb)], L^Pb = 1,4-bis-tert-butyl-dimethylsilyl-2,3-bis-phenyl-plumbolyl) towards the reactive pnictogen precursors P₄, pentaphosphaferrocene, and pentaarsaferrocene ([Cp*Fe(η⁵-E₅)] (Cp* = η⁵-C₅Me₅, E = P, As)) is reported. The reaction with P₄ afforded a phospholyl lithium complex, via lead-phosphorus exchange, while the reactions with [Cp*Fe(η⁵-E₅)] yielded the first examples of Pb–Fe–Li heterotrimetallic triple-decker polypnictogenides with three different deck motifs.