1,2-Acyl migration with α-imino rhodium carbenoids leading to substituted 1-naphthols

Tomoya Miura; Shunsuke Moritani; Yota Shiratori; Masahiro Murakami

doi:10.1039/D1CC06349A

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1,2-Acyl migration with α-imino rhodium carbenoids leading to substituted 1-naphthols†

Tomoya Miura,

‡*^a Shunsuke Moritani,

^a Yota Shiratori^a and Masahiro Murakami*^a

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* Corresponding authors

^a Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan
E-mail: tmiura@okayama-u.ac.jp, murakami@sbchem.kyoto-u.ac.jp

Abstract

A unique method for the synthesis of substituted 1-naphthols by a rhodium(II)-catalysed ring-expansion reaction of 2-triazolyl-1-indanone derivatives is reported. 1,2-Acyl migration occurs with an intermediate α-imino rhodium carbenoid generated from the triazolyl moiety.

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DOI: https://doi.org/10.1039/D1CC06349A
Article type: Communication
Submitted: 11 Nov 2021
Accepted: 21 Jan 2022
First published: 22 Jan 2022

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Chem. Commun., 2022,58, 2710-2713

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1,2-Acyl migration with α-imino rhodium carbenoids leading to substituted 1-naphthols

T. Miura, S. Moritani, Y. Shiratori and M. Murakami, Chem. Commun., 2022, 58, 2710 DOI: 10.1039/D1CC06349A

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Chemical Communications

1,2-Acyl migration with α-imino rhodium carbenoids leading to substituted 1-naphthols†

Abstract

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1,2-Acyl migration with α-imino rhodium carbenoids leading to substituted 1-naphthols

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