A new and efficient approach to a series of novel multifunctionalized spirocyclopentenone scaffolds through Piancatelli rearrangement was developed under metal-free conditions. This method has been successfully applied to O–, N– and C–nucleophiles with excellent yields.
P. R. Solanke, R. Cinsani, K. Nayani, P. S. Mainkar and S. Chandrasekhar, Chem. Commun., 2022, 58, 5530 DOI: 10.1039/D2CC00050D
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