Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer

Luciano Barluzzi; Nadir Jori; Tianyi He; Thayalan Rajeshkumar; Rosario Scopelliti; Laurent Maron; Paul Oyala; Theodor Agapie; Marinella Mazzanti

doi:10.1039/D2CC00473A

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Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer†

Luciano Barluzzi,‡^a Nadir Jori,

‡^a Tianyi He,^b Thayalan Rajeshkumar,^c Rosario Scopelliti,

^a Laurent Maron,

*^c Paul Oyala,

^b Theodor Agapie

*^b and Marinella Mazzanti

*^a

Author affiliations

* Corresponding authors

^a Group of Coordination Chemistry, Insititut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
E-mail: marinella.mazzanti@epfl.ch

^b Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA

^c Laboratoire de Physique et Chimie des Nano-objets, Institut National des Sciences Appliquées, 31077 Toulouse, Cedex 4, France

Abstract

The reaction of a terminal Mo(II) nitride with a U(III) complex yields a heterodimetallic U–Mo nitride which is the first example of a transition metal-capped uranium nitride. The nitride is triply bonded to U(V) and singly bonded to Mo(0) and supports a U–Mo interaction. This compound shows reactivity toward CO oxidation.

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DOI: https://doi.org/10.1039/D2CC00473A
Article type: Communication
Submitted: 24 Jan 2022
Accepted: 10 Mar 2022
First published: 10 Mar 2022

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Chem. Commun., 2022,58, 4655-4658

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Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer

L. Barluzzi, N. Jori, T. He, T. Rajeshkumar, R. Scopelliti, L. Maron, P. Oyala, T. Agapie and M. Mazzanti, Chem. Commun., 2022, 58, 4655 DOI: 10.1039/D2CC00473A

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Chemical Communications

Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer†

Abstract

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Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer

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