Issue 29, 2022
From the journal:

Chemical Communications

Nickel-catalyzed alkoxycarbonylation of aryl iodides with 1 atm CO†

Ning Liu,‡a   Xianqing Wu,‡a   Chenglong Wang,a   Jingping Qu ORCID logo a  and  Yifeng Chen ORCID logo *a  

* Corresponding authors

a Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China
E-mail: yifengchen@ecust.edu.cn

Abstract

A nickel-catalyzed alkoxycarbonylation of aromatic iodides with alcohols under atmospheric pressure of carbon monoxide is presented here. This operationally simple protocol allows the facile synthesis of (hetero)aromatic esters, exhibiting broad substrate scope with excellent functional group tolerance. Various primary and secondary aliphatic alcohols as well as phenols are suitable for this transformation.

Graphical abstract: Nickel-catalyzed alkoxycarbonylation of aryl iodides with 1 atm CO

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Article information

DOI
https://doi.org/10.1039/D2CC00876A
Article type
Communication
Submitted
12 Feb 2022
Accepted
11 Mar 2022
First published
12 Mar 2022

Chem. Commun., 2022,58, 4643-4646

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Nickel-catalyzed alkoxycarbonylation of aryl iodides with 1 atm CO

N. Liu, X. Wu, C. Wang, J. Qu and Y. Chen, Chem. Commun., 2022, 58, 4643 DOI: 10.1039/D2CC00876A

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