Covalent immobilization of TEMPO at carbon and gold via an aliphatic –(CH2)6– linker was achieved via cathodic grafting of a diamagnetic precursor, tetramethylpiperidine, with subsequent >NH to >NO oxidation to give TEMPO-capped paramagnetic interfaces (ΓTEMPO = 5.2 × 10−10 mol cm−2); catalytic and spin switching potential of the thus prepared systems was demonstrated.
V. Romanovs, V. Sidorkin, E. Doronina and V. Jouikov, Chem. Commun., 2022, 58, 10520 DOI: 10.1039/D2CC01520J
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