Issue 83, 2022
From the journal:

Chemical Communications

Metal-mediated rearrangement of 1,2-diphenylhydrazine to ortho-semidine upon reaction with dichlorotris(triphenylphosphine)ruthenium(ii)†

Nicolas Cena, ORCID logo a   Andrew J. Peloquin, ORCID logo b   Jerry A. Boatz, ORCID logo c   Sarah Costa,d   Steven R. Gralinski,d   Alan L. Balch ORCID logo *d  and  Kamran B. Ghiassi ORCID logo *c  

* Corresponding authors

a HX5, LLC, Air Force Research Laboratory, Aerospace Systems Directorate, Edwards AFB, California 93524, USA

b Department of Chemistry and Chemistry Research Center, Laboratories for Advanced Materials, United States Air Force Academy, Colorado Springs, Colorado, USA

c Air Force Research Laboratory, Aerospace Systems Directorate, Edwards AFB, California 93524, USA
E-mail: kamran.ghiassi@us.af.mil

d Department of Chemistry, University of California, Davis, USA
E-mail: albalch@ucdavis.edu

Abstract

Reaction between RuCl2(PPh3)3 and 1,2-diphenylhydrazine resulted in rearrangement and coordination of ortho-semidine. The product, RuCl2(PPh3)2(κ2-NH2-1,2-C6H4-NHPh), was characterized spectroscopically and the molecular structure was conclusively determined using X-ray crystallography. Computational chemistry was employed to probe the energetics surrounding the rearrangement reaction and product.

Graphical abstract: Metal-mediated rearrangement of 1,2-diphenylhydrazine to ortho-semidine upon reaction with dichlorotris(triphenylphosphine)ruthenium(ii)

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D2CC04500A
Article type
Communication
Submitted
12 Aug 2022
Accepted
18 Sep 2022
First published
19 Sep 2022

Chem. Commun., 2022,58, 11673-11676

Author version available


Download author version (PDF)

Permissions

Request permissions

Metal-mediated rearrangement of 1,2-diphenylhydrazine to ortho-semidine upon reaction with dichlorotris(triphenylphosphine)ruthenium(II)

N. Cena, A. J. Peloquin, J. A. Boatz, S. Costa, S. R. Gralinski, A. L. Balch and K. B. Ghiassi, Chem. Commun., 2022, 58, 11673 DOI: 10.1039/D2CC04500A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements