In situ activation of COOH-functionalized ZIF-90-enabled reductive CO2N-formylation

Abstract

A heterogeneous ZIF-90-based catalyst functionalized with COOH and with a porous structure was facilely prepared for efficient CO₂ adsorption and activation to undergo reductive N-formylation with a wide range of amines (15 examples) to furnish N-formamides (78–94% yields). The –COO⁻ species generated by an in situ interaction with amine acts as a key species for activating hydrosilane to capture CO₂, and remarkably facilitates a cascade C–N coupling and hydrogenation process. Our findings show a facile strategy for the rational construction of robust active sites for reductive CO₂ valorization.