Issue 86, 2022
From the journal:

Chemical Communications

Cooperative Cu/Pd-catalyzed borocarbonylation of ethylene†

Yang Yuan,a   Jian-Xing Xua  and  Xiao-Feng Wu ORCID logo *ab  

* Corresponding authors

a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, P. R. China
E-mail: xwu2020@dicp.ac.cn

b Leibniz-Institut für Katalyse e. V. Albert-Einstein-Strasse 29a, Rostock, Germany
E-mail: Xiao-Feng.Wu@catalysis.de

Abstract

We report here a cooperative Cu/Pd-catalyzed multi-component borocarbonylation of ethylene with aryl iodides. A variety of synthetically useful β-boryl ketones were assembled from the most basic C1 (CO) and C2 (ethylene) building blocks in good yields.

Graphical abstract: Cooperative Cu/Pd-catalyzed borocarbonylation of ethylene

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Article information

DOI
https://doi.org/10.1039/D2CC04907D
Article type
Communication
Submitted
06 Sep 2022
Accepted
05 Oct 2022
First published
07 Oct 2022

Chem. Commun., 2022,58, 12110-12113

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Cooperative Cu/Pd-catalyzed borocarbonylation of ethylene

Y. Yuan, J. Xu and X. Wu, Chem. Commun., 2022, 58, 12110 DOI: 10.1039/D2CC04907D

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