Phosphaacene as a structural analogue of thienoacenes for organic semiconductors

Kyohei Matsuo; Rina Okumura; Hironobu Hayashi; Naoki Aratani; Seihou Jinnai; Yutaka Ie; Akinori Saeki; Hiroko Yamada

doi:10.1039/D2CC05122B

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Phosphaacene as a structural analogue of thienoacenes for organic semiconductors†

Kyohei Matsuo,

*^a Rina Okumura,^a Hironobu Hayashi,

^a Naoki Aratani,

^a Seihou Jinnai,

^b Yutaka Ie,

^b Akinori Saeki

^c and Hiroko Yamada

*^a

Author affiliations

* Corresponding authors

^a Division of Materials Science, Nara Institution of Science and Technology (NAIST), 8916-5 Takayama-cho, Ikoma, Nara, Japan
E-mail: kmatsuo@ms.naist.jp, hyamada@ms.naist.jp

^b The Institute of Scientific and Industrial Research (SANKEN), Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan

^c Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, Japan

Abstract

An air-stable λ³-phosphinine-containing polycyclic aromatic compound without steric protection was synthesized and its charge transport properties were evaluated, which revealed moderate hole mobility. This research is the first experimental demonstration of the organic electronic applications of low-coordinate phosphorus compounds.

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Correction: Phosphaacene as a structural analogue of thienoacenes for organic se…

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DOI: https://doi.org/10.1039/D2CC05122B
Article type: Communication
Submitted: 16 Sep 2022
Accepted: 09 Nov 2022
First published: 14 Nov 2022
This article is Open Access

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Chem. Commun., 2022,58, 13576-13579

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Phosphaacene as a structural analogue of thienoacenes for organic semiconductors

K. Matsuo, R. Okumura, H. Hayashi, N. Aratani, S. Jinnai, Y. Ie, A. Saeki and H. Yamada, Chem. Commun., 2022, 58, 13576 DOI: 10.1039/D2CC05122B

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Chemical Communications

Phosphaacene as a structural analogue of thienoacenes for organic semiconductors†

Abstract

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Phosphaacene as a structural analogue of thienoacenes for organic semiconductors

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