Issue 98, 2022
From the journal:

Chemical Communications

Chiroptical induction with prism[5]arene alkoxy-homologs†

Xiaotong Liang,a   Yanling Shen,a   Dayang Zhou,b   Jiecheng Ji,a   Hongtao Wang,*a   Ting Zhao,a   Tadashi Mori, ORCID logo *b   Wanhua Wu ORCID logo a  and  Cheng Yang ORCID logo *a  

* Corresponding authors

a College of Architecture and Environment, Huaxi MR Research Center (HMRRC), Department of Radiology, West China Hospital, and Key Laboratory of Green Chemistry & Technology of Ministry of Education, Sichuan University, Chengdu 610064, China
E-mail: wanght@scu.edu.cn, yangchengyc@scu.edu.cn

b Department of Applied Chemistry, and Comprehensive Analysis Center, ISIR, Osaka University, Yamada-oka, Suita 565-0871, Japan
E-mail: tmori@chem.eng.osaka-u.ac.jp

Abstract

The complexation of prism[5]arenes with amino acid derivatives showed association constants of up to 107 M−1, significant CD with gabs of up to 0.8 × 10−2 and CPL with glum of 2 × 10−3. The absolute configuration-CD signal correlation was established. The CD spectra varied significantly with the substituents on the prism[5]arenes.

Graphical abstract: Chiroptical induction with prism[5]arene alkoxy-homologs

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Article information

DOI
https://doi.org/10.1039/D2CC05690A
Article type
Communication
Submitted
20 Oct 2022
Accepted
15 Nov 2022
First published
19 Nov 2022

Chem. Commun., 2022,58, 13584-13587

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Chiroptical induction with prism[5]arene alkoxy-homologs

X. Liang, Y. Shen, D. Zhou, J. Ji, H. Wang, T. Zhao, T. Mori, W. Wu and C. Yang, Chem. Commun., 2022, 58, 13584 DOI: 10.1039/D2CC05690A

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