Three adamantane-bearing macrocycles with pyrazine or tetrazine units afforded porous organic crystals possessing distinct surface properties of 1D pores, which captured multiple water molecules from the air or liquid water in a single-crystal-to-single-crystal fashion. The molecular structures of the macrocycles and water molecules were confirmed by X-ray analysis.
M. Tominaga, T. Hyodo, K. Mizuno, M. Kawahata and K. Yamaguchi, CrystEngComm, 2022, 24, 6449 DOI: 10.1039/D2CE01030E
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