Issue 48, 2022

Efficient hydrogen isotopic analysis with Cu–Fe/ZSM-5 zeolite as a cryogenic chromatographic stationary phase

Abstract

Materials as stationary phase are crucial for the chromatographic analysis of hydrogen gas isotopes. In this study, a Cu–Fe/ZSM-5 zeolite with ion-exchanged Fe3+–Cu2+ is prepared for H2/D2 chromatographic analysis. High-resolution H2/D2 separation is enabled within 4 min and their concentrations are quantitatively analyzed according to peak areas with high accuracy (R2 ≥ 0.999).

Graphical abstract: Efficient hydrogen isotopic analysis with Cu–Fe/ZSM-5 zeolite as a cryogenic chromatographic stationary phase

Supplementary files

Article information

Article type
Communication
Submitted
28 Sep 2022
Accepted
11 Nov 2022
First published
15 Nov 2022

CrystEngComm, 2022,24, 8350-8353

Efficient hydrogen isotopic analysis with Cu–Fe/ZSM-5 zeolite as a cryogenic chromatographic stationary phase

J. Zhang, H. Rong, X. Feng, P. Li, Y. Guan, Y. An and X. Zou, CrystEngComm, 2022, 24, 8350 DOI: 10.1039/D2CE01345B

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