Issue 39, 2022

Insights into the non-covalent interactions of hydrogen sulfide with fenchol and fenchone from a gas-phase rotational study

Abstract

The gas-phase non-covalent interactions in the endo-fenchol–H2S and fenchone–H2S complexes have been unveiled using rotational spectroscopy in a supersonic jet expansion and quantum chemical calculations. In endo-fenchol, the hydrogen bond HSH⋯OH together with dispersive interactions stabilizes the system. In fenchone, the weak interaction HSH⋯O[double bond, length as m-dash]C allows an internal dynamic of H2S.

Graphical abstract: Insights into the non-covalent interactions of hydrogen sulfide with fenchol and fenchone from a gas-phase rotational study

Supplementary files

Article information

Article type
Communication
Submitted
22 Jul 2022
Accepted
21 Sep 2022
First published
23 Sep 2022

Phys. Chem. Chem. Phys., 2022,24, 24007-24011

Insights into the non-covalent interactions of hydrogen sulfide with fenchol and fenchone from a gas-phase rotational study

N. Osseiran, E. M. Neeman, P. Dréan, M. Goubet and T. R. Huet, Phys. Chem. Chem. Phys., 2022, 24, 24007 DOI: 10.1039/D2CP03368B

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