Issue 16, 2022

A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope

Abstract

A sustainable and facile weak-base synthetic route to platinum N-heterocyclic carbene (NHC) complexes is disclosed. The mechanism of this reaction is also elucidated via experimental and computational investigations. This straightforward protocol is then used for the synthesis of novel Pt(II)-NHC complexes and its utility is further explored to access key Pt(0)-NHC precatalysts.

Graphical abstract: A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope

Supplementary files

Article information

Article type
Paper
Submitted
11 Mar 2022
Accepted
23 Mar 2022
First published
23 Mar 2022

Dalton Trans., 2022,51, 6204-6211

A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope

B. P. Maliszewski, I. Ritacco, M. Beliš, I. I. Hashim, N. V. Tzouras, L. Caporaso, L. Cavallo, K. Van Hecke, F. Nahra, C. S. J. Cazin and S. P. Nolan, Dalton Trans., 2022, 51, 6204 DOI: 10.1039/D2DT00504B

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