FeCoS2 polyhedral spherical nanoparticle decorated nitrogen doped hollow carbon nanofibers as high-performance self-supporting anodes for K-ion storage

Abstract

Herein, we present a freestanding and flexible 3D nanocomposite made of polyhedral spherical FeCoS₂ and nitrogen-doped hollow carbon nanofibers (FeCoS₂@N-HCNFs) that is synthesized through coaxial electrospinning, high-temperature calcination, and a facile solvothermal process. As a binder-free anode composite for potassium-ion batteries (PIBs), FeCoS₂@N-HCNF presents a high specific discharge capacity on the first lap (701.2 mA h g⁻¹ at 100 mA g⁻¹) and superior cycling stability (132.6 mA h g⁻¹ at 3200 mA g⁻¹ after 600 cycles). The impressive electrochemical performance can be ascribed to the unique 3D structure, such as the enormous specific surface area of the mesoporous structure beneficial for K⁺ transfer, the three-dimensional hollow carbon nanofiber scaffold enhances the structural stability, and polyhedral spherical FeCoS₂ improves the overall specific capacity. According to the above description, the FeCoS₂@N-HCNF anode is a promising candidate for advanced potassium-ion batteries.