Coupling nanobubbles in 2D lateral heterostructures

Abstract

Two-dimensional transition metal dichalcogenides provide flexible platforms for nanophotonic engineering due to their exceptional mechanical and optoelectronic properties. For example, continuous band gap tunability has been achieved in 2D TMDs by elastic strain engineering. Localized elastic deformations in nanobubbles behave as “artificial atoms” with a spatially varying band gap resulting in funnelling of excitons and photocarriers. Here we present a new method of nanobubble fabrication in monolayer 2D lateral heterostructures using high temperature superacid treatment. We fabricated MoS₂ and WS₂ nanobubbles and performed near-field imaging with nanoscale resolution using tip-enhanced photoluminescence (TEPL) spectroscopy. TEPL nanoimaging revealed the coupling between MoS₂ and WS₂ nanobubbles with a large synergistic PL enhancement due to the plasmonic tip, hot electrons, and exciton funnelling. We investigated the contributions of different enhancement mechanisms, and developed a quantum plasmonic model, in good agreement with the experiments. Our work opens new avenues in exploration of novel nanophotonic coupling schemes.