High strength composites from low-value animal coproducts and industrial waste sulfur

Abstract

Herein we report high strength composites prepared by reaction of sulfur, plant oils (either canola oil or sunflower oil) and brown grease. Brown grease is a high-volume, low value animal fat rendering coproduct that represents one of the most underutilized products of agricultural animal processing. Chemically, brown grease is primarily comprised of triglycerides and fatty acids. The inverse vulcanization of the unsaturated units in triglycerides/fatty acids upon their reaction with sulfur yields CanBG_x or SunBG_x (x = wt% sulfur, varied from 85–90%). These composites were characterized by infrared spectroscopy, dynamic mechanical analysis (DMA), mechanical test stand analysis, elemental analysis, and powder X-ray diffraction. CanBG_x and SunBG_x composites exhibit impressive compressive strengths (28.7–35.9 MPa) when compared to other materials such as Portland cement, for which a compressive strength of ≥17 MPa is required for residential building. Stress–strain analysis revealed high flexural strengths of 6.5–8.5 MPa for CanBG_x and SunBG_x composites as well, again exceeding the range of ∼2–5 MPa for ordinary Portland cements. The thermal properties of the composites were assessed by thermogravimetric analysis, revealing decomposition temperatures ranging from 223–226 °C, and by differential scanning calorimetry. These composites represent a promising new application for low value animal coproducts having limited value to be used as organic crosslinkers in the atom-efficient inverse vulcanization process to yield high sulfur-content materials that have impressive mechanical properties.