Aromatic sensitizers in luminescent hybrid films

Abstract

Atomic layer deposition offers a unique set of design possibilities due to the vast range of metal and organic precursors that can be used and combined. In this work, we have combined lanthanides with aromatic aids as strongly absorbing sensitizers to form highly luminescent thin films. Terephthalic acid is used as a base sensitizer, absorbing shorter wavelengths than 300 nm. The absorption range is extended towards the near-UV and blue range by increasing the aromatic system and adding functional groups that have strong red-shifting effects. While terbium and europium provide green and red emission, yttrium allows emission from the sensitizer itself spanning the whole color range from purple, blue and green to red. Many organic dye molecules show very high luminescence quantum yields and several of the molecules and materials investigated in this work show bright luminescence.