A Cu(ii) complex supported on Fe3O4@SiO2 as a magnetic heterogeneous catalyst for the reduction of environmental pollutants

Abstract

Today, the presence of pollutants in the environment has become one of the serious problems and concerns of human beings. To eliminate these pollutants, researchers have made many efforts. One of the most important of these efforts is the reduction of such contaminants in the presence of effective catalysts. Two of the most important and widespread types of these pollutants are nitro compounds and organic dyes. In this paper, we report the synthesis of an efficient and reusable magnetic catalyst using Fe₃O₄@SiO₂ core–shell nanoparticles (NPs), N-(4-bromophenyl)-N′-benzoylthiourea, and copper(II). Specifically, the Cu(II)-N-(4-bromophenyl)-N′-benzoylthiourea complex supported on Fe₃O₄-core magnetic NPs (CM)/SiO₂-shell (SS) (CM@SS-BBTU-Cu(II)) has been prepared. CM@SS-BBTU-Cu(II) was characterized by FT-IR (Fourier transform infrared spectroscopy), XRD (X-ray diffraction), TEM (transmission electron microscopy), HRTEM (high resolution transmission electron microscopy), FFT (fast Fourier transform), VSM (vibrating sample magnetometry), TG-DTA (thermogravimetry-differential thermal analysis), STEM (scanning transmission electron microscopy), EDS (energy-dispersive X-ray spectroscopy), and elemental mapping. The synthesized CM@SS-BBTU-Cu(II) was applied for the reduction of 4-nitrophenol (4-NP), Congo red (CR), and methylene blue (MB) in the presence of NaBH₄ (sodium borohydride) at room temperature. CM@SS-BBTU-Cu(II) can be recycled and reused 5 times. Our results displayed that the performance of the catalyst was not significantly reduced by recycling.