A novel poly(2-mercaptobenzothiazole) coated magnetic nanoadsorbent derived from ZIF-8 for preconcentration/determination of palladium and silver

Abstract

Herein, a novel poly(2-mercaptobenzothiazole) coated magnetic nanoadsorbent derived from zeolitic-imidazole framework-8 (ZIF-8) was synthesized and then employed for the extraction/preconcentration of trace amounts of palladium and silver in various real matrixes. In this way, magnetite was fabricated first, and then functionalized with tetraethyl orthosilicate. After that, the synthesized magnetite@silica was coated with the ZIF-8 to obtain magnetic ZIF-8. Afterward, the magnetic ZIF-8 was pyrolyzed under the protection of a nitrogen atmosphere to get a magnetic carbon nanoadsorbent. Finally, the magnetic carbon was functionalized with a conductive polymer (poly-2-mercaptobenzothiazole). Fabrication of the nanoadsorbent was affirmed with scanning and transmission electron microscopies, elemental analysis, X-ray diffraction, Fourier transform infrared spectroscopy, and vibrating sample magnetometry. The method is linear from 0.25 to 200 μg L⁻¹ for silver, and from 0.5 to 250 μg L⁻¹ for palladium. The detection limits are 0.07 and 0.15 μg L⁻¹ for Ag and Pd, respectively. The precision was evaluated at three concentration levels (1, 75, 200 μg L⁻¹, n = 5) and all the relative standard deviation (RSD) values were lower than 10.3%. In the end, the new method was utilized for the preconcentration/determination of trace amounts of palladium and silver in various real matrixes, satisfactorily (relative recovery: 86% to 104%; RSD%: 4.0–9.5%).