Issue 23, 2022
From the journal:

Chemical Science

Arsolyl-supported intermetallic dative bonding†

Ryan M. Kirk ORCID logo a  and  Anthony F. Hill ORCID logo *a  

* Corresponding authors

a Research School of Chemistry, Australian National University, Canberra, A.C.T., Australia
E-mail: a,hill@anu.edu.au

Abstract

The first examples of late transition metal η5-arsolyls Image ID:d2sc01200f-t1.gif (L = CO, P(OMe)3; R = Ph, Me, Et, SiMe3; R′ = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = PtII, AuI, HgII) through both conventional As → M and polar-covalent (dative) Co → M interactions.

Graphical abstract: Arsolyl-supported intermetallic dative bonding

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Article information

DOI
https://doi.org/10.1039/D2SC01200F
Article type
Edge Article
Submitted
26 Feb 2022
Accepted
02 May 2022
First published
04 May 2022
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2022,13, 6830-6835

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Arsolyl-supported intermetallic dative bonding

R. M. Kirk and A. F. Hill, Chem. Sci., 2022, 13, 6830 DOI: 10.1039/D2SC01200F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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