Effect of particle size on the stripping dynamics during impact of liquid marbles onto a liquid film

Abstract

The robust attachment of particles at fluid interfaces is favorable for engineering new materials due to the large capillary energy, but it meets significant challenges when particle removal is a requirement. A previous study has shown that soap films can be utilized to achieve particle separation from liquid marbles. Here, we investigate the effects of particle size on the particle separation from liquid marbles using fast dynamics of drop impact on a soap film. Experimental observations disclose that the fast dynamics of the liquid marble involves coalescence, bouncing, stripping, or tunneling through the film by controlling the falling height and drop volume. More importantly, the active regime of the stripping mode can be selective-controlled by tuning the particle size, and the smaller stabilizing particles make a wider stripping regime. This is attributed to the smaller change of the surface energy resulting from the larger surface tension of LMs wrapped by smaller particles. Theoretical analysis reveals that the stripping thresholds are determined by the energy competition between kinetic energy, the increased surface energy and viscous dissipation, which offers important insights into particle separation by tuning the particle size. The present study provides guidelines for applications that involve phase separation.