Issue 16, 2023
From the journal:

Chemical Communications

Dicopper(ii) paddle-wheel metal–organic frameworks for high propyne storage under ambient conditions†

Xing-Ping Fu,ab   Ji-Wei Shen,a   Ling Chen,*a   De-Xin Zhong,a   Yu-Ling Wang ORCID logo *a  and  Qing-Yan Liu ORCID logo *a  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Jiangxi Normal University, Nanchang 330022, Jiangxi, P. R. China
E-mail: qyliuchem@jxnu.edu.cn, ylwang@jxnu.edu.cn

b Department of Ecological and Resources Engineering, Fujian Key Laboratory of Eco-industrial Green Technology, Wuyi University, Wuyishan 354300, Fujian, P. R. China

Abstract

Fluorinated dicopper(II) metal–organic framework JXNU-16F with 1,3,5-tri(3,5-bifluoro-4-carboxyphenyl)benzene ligands and nonfluorinated JXNU-16 exhibit high propyne uptakes of 443 and 496 cm3 g−1 under ambient conditions, respectively. Their remarkable propyne uptakes result from suitable pore spaces and strong propyne⋯propyne interactions amongst the adsorbed propyne molecules, as revealed by computational simulations.

Graphical abstract: Dicopper(ii) paddle-wheel metal–organic frameworks for high propyne storage under ambient conditions

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Article information

DOI
https://doi.org/10.1039/D2CC06684J
Article type
Communication
Submitted
08 Dec 2022
Accepted
26 Jan 2023
First published
26 Jan 2023

Chem. Commun., 2023,59, 2263-2266

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Dicopper(II) paddle-wheel metal–organic frameworks for high propyne storage under ambient conditions

X. Fu, J. Shen, L. Chen, D. Zhong, Y. Wang and Q. Liu, Chem. Commun., 2023, 59, 2263 DOI: 10.1039/D2CC06684J

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