Issue 31, 2023

Chiral carbonyl hypoiodites

Abstract

Three chiral carbonyl hypoiodites, R–C(O)OI, have been prepared from N-protected (S)-valine to give the ligand-stabilised (S)-valinoyl hypoiodite complexes with 4-dimethylaminopyridine, 4-pyrrolidinopyridine, and 4-morpholinopyridine as the stabilising ligands. The identity of the complexes was established by NMR (1H, 13C, 1H–15N HMBC) and single crystal X-ray diffraction analysis.

Graphical abstract: Chiral carbonyl hypoiodites

Supplementary files

Article information

Article type
Communication
Submitted
17 Jan 2023
Accepted
24 Mar 2023
First published
24 Mar 2023
This article is Open Access
Creative Commons BY license

Chem. Commun., 2023,59, 4648-4651

Chiral carbonyl hypoiodites

M. Mattila, K. Rissanen and J. S. Ward, Chem. Commun., 2023, 59, 4648 DOI: 10.1039/D3CC00259D

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